The item site can only be specified on the purchase agreement line if the dimension is enabled in the Product dimension groups ...

The item site can only be specified on the purchase agreement line if the dimension is enabled in the Product dimension groups page. The item site is used as a matching criterion when you create a release order from a purchase order line that is linked to the purchase agreement. If the field on the purchase agreement line is blank, any value can be entered on the release order line.
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