The Remove-MSOLFederatedDomain cmdlet removes the specified single sign-on domain from Office 365 and the associated relying ...

The Remove-MSOLFederatedDomain cmdlet removes the specified single sign-on domain from Office 365 and the associated relying party trust settings in Active Directory Federation Services 2.0. 
      
Note: If the domain specified has objects associated with it, you will not be able to remove the domain.
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